So, we want a Moon base with minimal resupply from Earth; hence the reliance on ISRU and bootstrapping. Eventually we will tap the resources of NEOs and Mars along with its moonlets and our reliance on Earth for anything besides dollars will be about zero. At first we will upport complex, lightwt and electronic items but eventually we will make our electronics on the Moon.
In the previous post I discussed oxygen and volatiles-H, He, N and C.
We can produce cast basalt, glass and GGCs, cement, plaster, iron, magnesium and sulfur on the Moon w/o upported chemical reagents. For more info see:
http://www.moonminer.com/Moondust_index.htmlhttp://www.moonminer.com/Recent-Documents.htmlhttp://www.moonminer.com/Lunar-Manufacturing-Index.htmlTitanium and aluminum will require chloride fluxes. CaCl2 for Ti refining FFC cells and LiCl and NaCl for Al production by the ALCOA process. see:
http://www.nas.nasa.gov/About/Education ... s/V-5.htmlquote: Two typical compositions of the electrolyte (in weight percent) are: AlCl3(5), NaCl(53), LiCl(40), MgCl2(0.5), KCl(O.5), and CaCl2(1); and AlCl3(5 ± 2), NaCl(53), and LiCl(42 ± 2). The aluminum chloride concentration must be carefully controlled to ensure trouble-free operation.
An operating life of nearly 3 years is claimed for the electrodes when the oxide content of the electrolyte remains below 0.03 weight percent. The energy consumption of the cell is 9 kWhr/kg of aluminum produced.
We will also need graphite electrodes for both FFC cells and Al electrolysis. Since graphite electrodes are made of carbon powder bonded with pitch, we will have to upport at first and eventually produce pitch on the Moon with some organic chemist's magic from C, H and N. So we will have to mine plenty of solar wind implanted carbon.
Chlorine is not abundant on the Moon, niether is lithium. We will have to upport LiCl in salt form. We could extract sodium from regolith and combine it with Cl upported in the form of copper or zinc chloride salts that we decompose on the Moon to get Cl and some Zn and Cu too. Plastic bags of salts might amass less than heavy insulated tanks of liquid chlorine.
While I don't know of a lunar lithium source, we could someday tap Cl from volcanic glass. From19.5 million tons of volcanic glass, that's in the range of regolith mining shemes proposed for mining volatiles, iron fines, etc. We'd get 1.1 million tons of oxygen; 8,800 tons of sulfur; 5,800 tons of zinc; 1,900 tons of chlorine; 1,900 tons of iron; 1,500 tons of nickel, 510 tons of copper, 310 tons of gallium.
http://www.moonminer.com/Lunar_Volcanic_Glass.html Chlorine is also used to synthesize silicones and produce silane and in some silicon purification processes. It's pretty useful stuff. We need to make table salt too. So we will be upporting Cl salts at first and eventually mine volcanic glass to cut this particular cord with Earth.
Since titanium has excellent chloride corrosion resistance we should make Cl handling equipment (piping, pumps, valves, etc.) out of titanium.